Name | methacrylic anhydride |
Synonyms | methacrylic anhydride Methacryloyl anhydride methacrylicacidanhydride 1-Methylacrylic anhydride Methacrylic acid anhydride Methylacrylic acid anhydride 2-methylprop-2-enoic anhydride 2-Methylacrylic acid anhydride 2-methyl-2-propenoicacianhydride 2-Propenoicacid,2-methyl-,anhydride 2-Propenoic acid, 2-methyl-, anhydride |
CAS | 760-93-0 |
EINECS | 212-084-8 |
InChI | InChI=1/C8H10O3/c1-5(2)7(9)11-8(10)6(3)4/h1,3H2,2,4H3 |
InChIKey | DCUFMVPCXCSVNP-UHFFFAOYSA-N |
Molecular Formula | C8H10O3 |
Molar Mass | 154.17 |
Density | 1.04g/mLat 20°C |
Melting Point | -20°C |
Boling Point | 87°C13mm Hg(lit.) |
Flash Point | 184°F |
Water Solubility | 98g/L at 20℃ |
Solubility | Miscible with ethanol and ether. |
Vapor Presure | 90Pa at 20℃ |
Appearance | clear liquid |
Color | Colorless to Light yellow to Light orange |
BRN | 1761982 |
Storage Condition | under inert gas (nitrogen or Argon) at 2-8°C |
Stability | Stable. Flammable. Moisture-sensitive. |
Sensitive | Moisture Sensitive |
Refractive Index | n20/D 1.453(lit.) |
Hazard Symbols | Xn - Harmful |
Risk Codes | R20 - Harmful by inhalation R37/38 - Irritating to respiratory system and skin. R41 - Risk of serious damage to eyes |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S39 - Wear eye / face protection. |
UN IDs | UN 3265 8/PG 2 |
WGK Germany | 1 |
RTECS | OZ5700000 |
FLUKA BRAND F CODES | 10-21 |
TSCA | Yes |
HS Code | 29161900 |
Hazard Class | 8 |
Packing Group | II |
LogP | 1.23 |
NIST chemical information | information provided by: webbook.nist.gov (external link) |
EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
Application | 2-methacrylic anhydride is a strong esterifying agent, it is a necessary reagent for the preparation of methacrylic sulfur Ester and methacrylate Ester, especially the ester of tertiary alcohol. At the same time, it can be used as a crosslinking agent for polymerization reaction in the synthesis of photocurable coatings, crosslinked resins and other materials. |
preparation | 1mol of sodium methacrylate, 3mol of propionyl chloride and 0.1mol of polymerization inhibitor are added to the reactor, the temperature was raised to 90-100 ° C. And refluxed for 8 hours. After distillation and shunting, fractions at 100-105 ° C. Were collected to obtain 2-methacrylic anhydride. The purity of the product was 98.98%, and the yield of the product was 98.33%. |
Application | for the synthesis of photocurable coatings, cross-linked resins and other materials |
toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |